Derivation of dynamical density functional theory using the projection operator technique.
نویسندگان
چکیده
Density functional theory is a particular case of a general theory of conjugate variables that serves as the basis of the projection operator technique. By using this technique we derive a general dynamical version of density functional theory which involves a generalized diffusion tensor. The diffusion tensor is given by a Green-Kubo expression. For Brownian dynamics of dilute colloidal suspensions, the standard dynamical density functional theory is recovered.
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عنوان ژورنال:
- The Journal of chemical physics
دوره 131 24 شماره
صفحات -
تاریخ انتشار 2009